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Kalk questions

Discussion in 'General Discussion' started by Bud, Feb 22, 2012.

  1. Bud Loves Bacon Website Team Board of Directors Leadership Team GIRS Member Vendor

    West Des Moines, IA
    Ratings:
    +1,823 / 14 / -0
    I've been considering making the transition to Kalkwasser.  I've been reading up and testing a few things.  I've been following a good discussion on the Algae Scrubber site here:


    http://algaescrubber.net/forums/showthread.php?1637-Keeping-up-Ca-Mg-and-str&p=17065



    And an excellent article on that thread referencing vinegar and Kalk here:
    http://www.reefscapes.net/articles/...asser.html
    So I took 5g of RO/DI and poured in 100ml Vinegar (white, 5%) per the directions for the 'starting amount', which is 5ml/qt, then mixed in 10 tsp of BRS Kalk an stirred.  I let it sit for a day and the water is cloudy.  There is about a tsp of sediment at the bottom, but the water is cloudy like I poured in a cup or so of milk.  This is in an orange home depot bucket so I can see it well.  Also the water has a skin layer.
    What I had calculated is that I need 30% saturated solution so match the strength of the water in my ATO right now, which has BRS Alk mixed in.  So I took a 2 qt container and scooped out 1.5g of sat soln and filled with RODI.  I have yet to test the pH and Alk of this solution to see if it matches the BRS mix (which was pH of 11.0 and Alk of 30.4).
    I found out after I did this (haven't used the solution yet) that the correct vinegar procedure is to dissolve the Kalk powder in the vinegar first, so that it fixes all the CO2, then add the RO/DI.  So perhaps this is my mistake.  I would appreciate hearing from anyone who mixes vinegar and Kalk.  Honestly after reading that article I can't imagine why anyone wouldn't.
    but here's the next issue.
    I stopped into Seascapes to see if they had some carbon (by the way, they're dropping BRS products because "They're crap" according to Scott).  I had a discussion with Scott about the BRS products and he told me that he was originally dosing the Kalk into the 1200 and wasn't getting good growth, and the pH was actually dropping.  He switched to Brightwell Kalk+2 and he said the change was dramatic.  He said that's pretty much all they use (a few other Brightwell products too, like Potassium).  He said he just mixes it up in a 5g jug and shakes it good and lets it sit for a while (he didn't define the length of time, but I have the feeling it's not long) then cracks open the valve and drips the whole thing in.  He even said that when it gets to the point where there's a lot of sediment in the container, he dumps that in the tank too!!
    Now everyone is telling me not to do that, because the sediment can "burn holes in your corals", etc.  Scott just shrugged it off and said "Look at the tank" and he's right, growth is doubling every month in that tank, it's stunning.  The Kalk+2 has Magnesium and Strontium and he said without Strontium your corals can't fix Calcium well, so he attributes the success of Kalk+2 of BRS Kalk to the fact that it's just a better all around product due to the additional ingredients.
    So what are everyone's feelings on these point?  Do I need to worry about the cloudy Kalkwasser?  Should I just throw in out and go with the Kalk+2?
     
  2. Waverz

    Waverz Expert Reefkeeper

    Ratings:
    +5 / 0 / -0
    Dripping lime water is a tried and true method. I've never used it in conjunction with vinegar but I do use it for most of my Alkalinity and Calcium needs. I just use 2 tsp per gallon of RODI in my ATO. It does a pretty good job of keeping my levels up but as demand increases I use my CA reactor to make up for the rest. The added benefit of dripping limewater is it keeps the pH up which is really nice while running in conjuction with a Ca Ractor.

    The sediment won't affect anything as long as it doesn't make direct contact with corals. I actually use a piece of ridgid airline tubing with a "J" bent into it to avoid sucking up the excess powder into my tank. This also keeps my ATO pump from getting clogged pre maturally.

    As far as BRS products being crap, personally I think it's all pretty much the same stuff made in the same factory with a different label.

    I've never heard of Kalk+2 but I do like the fact it adds mag as well as stronium, both are very important and are used quickly. I might have to give it a try.
     
  3. Bud Loves Bacon Website Team Board of Directors Leadership Team GIRS Member Vendor

    West Des Moines, IA
    Ratings:
    +1,823 / 14 / -0
    That's what I thought, I mean people use Mrs. Wages Pickling Lime from the grocery store for pete's sake. I just think the benefits of Kalk +2 with the addition of Strontium and Magnesium make sense, so I have a question into Brightwell to see if vinegar affects these.

    You should read that article. Mixing the Kalk powder in vinegar apparently causes the Kalk to dissolve completely, and there is no sediment at all. This also apparently increases the available calcium, so if you have to run a reactor now you might not have to using this technique I guess.

    Oooh and I just got the reply from Chris Brightwell himself!

     
  4. Tholton33

    Tholton33 Well-Known ReefKeeper

    537
    Ratings:
    +0 / 0 / -0
    Wouldnt the water become completely saturated no matter how much pickling lime you add? The rest left as sediment until you add more water and more would dissolve? Or am I thinking too simply.
     
  5. Foo

    Foo Well-Known ReefKeeper

    524
    Ratings:
    +4 / 0 / -0
    http://reefkeeping.com/issues/2005-01/rhf/index.php

    This is a good read.
     
  6. mthomp

    mthomp Inactive User

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    +0 / 0 / -0
    I personally do not like adding the kalk to my ato resevoir as I am concerned about it gumming up my ato pump, so I use this.

    http://www.bulkreefsupply.com/store/products/reactors/kalkwasser-reactor/two-little-fishies-kalkwasser-stirrer-reactor-300.html
     
  7. Waverz

    Waverz Expert Reefkeeper

    Ratings:
    +5 / 0 / -0
    Good point, eventually it will gum up the pump but I am prepared.  I use an Aqualifter pump and replacement diaphragm kits are $3.  If I had the room I would love to run a stirrer.  I used to run a Deltec stirrer back in the day but that was back when I had room and wasn't confined to cramming every thing in a 22" x 22" area.
    /DesktopModules/ActiveForums/themes/_default/emoticons/biggrin.gif
     
  8. Jamie

    Jamie Well-Known ReefKeeper Vendor

    591
    Ratings:
    +24 / 0 / -0
  9. Bela

    Bela Inactive User

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    +0 / 0 / -0
    If you are using just RO, there is no real reason to measure things out, unless it just makes you feel better about it. You are only going to be able to dissolve a certain amount, the rest of which will settle to the bottom. I basically take 1/8 of a bag of pickling lime and dump it in my reservior, shake it up real well, and let it settle. Once the reservior is down to about 1/4 full I top it off with about 4-5 gallons fresh RO. The pouring itself gets everything nice an mixed up. I just disconnect my ATO for about an hours until everything settles.

    Also, regarding pumps, I just dunk my pump in 50/50 vinegar and water and let it run for about 12-24 hours every 4 months or so. Seems to be working ok.
     
  10. Bud Loves Bacon Website Team Board of Directors Leadership Team GIRS Member Vendor

    West Des Moines, IA
    Ratings:
    +1,823 / 14 / -0
    Kalk stirrers work when you want to dose saturated limewater. That is not what I want to do because my alk uptake is not enough to mandate it, so it needs to be diluted, and that won't work with a kalk stirrer unless you have the means to control the dosage in relation to RODI top off. I guess the answer is 2 top off pumps, one direct to the tank and another through the kalk stirrer on a timer or controller, but that's not what I am going for currently. Maybe in the future though!

    Also you can't take advantage of vinegar with a kalk stirrer from what I understand, because the point is to dissolve the kalk in the vinegar first, then put it in the top off water. It doesn't work the other way around, not at least from what I'm understanding. Haven't read those link yet though...
     
  11. Jamie

    Jamie Well-Known ReefKeeper Vendor

    591
    Ratings:
    +24 / 0 / -0
    I think there is 2 different approaches or reasons hobbyist use kalk
    1. To simply control Ph with the added benefit of adding small amounts of alk and ca
    2. To control alk and ca with a single balanced additive when demand is low.

    If you demands aren't very high there is no need for the vinegar. You can just dose more kalk solution with the same results unless your Ph gets to high. If your demands are higher I think a 2 part or CA reactor is a better route to go.

    Basically adding vinegar will get you closer to what a kalk reactor would do with RODI water I would think.
     
  12. Bela

    Bela Inactive User

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    +0 / 0 / -0
    Just looking through the thread, I noticed you were wanting to add vinegar to the mix as a magnesium supplement? (forgive me if this assumption is off, I skimmed, but didn't read through all 5 million pages lol). I am not sure how magnesium came into play, or would come into play in terms of the two compounds we are speaking of. The chemical compositions of vinegar and calcium hydoxide (kalk powder) are CH3COOH and Ca (OH)2, respectively. Even when we add H2O, or water, to the mix, I don't see how we are expected to come up with Mg. I am not chemist, though did have to go through more chemistry than I would like to admit (hated it), but I would expect the addition if vinegar to your RO to only increase the amount of calcium hydroxide that can be dissolved in solution slightly, alongside raising said solutions pH, again slightly, but that also doesn't seem to be your goal, thus leaving me a little confused.
     
  13. Bud Loves Bacon Website Team Board of Directors Leadership Team GIRS Member Vendor

    West Des Moines, IA
    Ratings:
    +1,823 / 14 / -0
    I said nothing about kalk and vinegar adding Mg. Brightwell Kalk+2 has Mg and Str added. Also the reefkeeping article mentions that regular old Kalk has traces of Mg and Str so I don't know if the brightwell stuff has more added or what.

    Read through the second link in the first post and the reefkeeping article. Adding vinegar will actually lower the pH of the mixture not raise it. There is some confusing chemistry and conflicting info between the 2 articles so I'm trying to get this all sorted out. Also the thread linked in the first post is becoming an excellent thread.
     
  14. Bela

    Bela Inactive User

    Ratings:
    +0 / 0 / -0
    Sorry, like I said, I skimmed the thread. On the first link, on the first page, your first post was asking the following: "How does Kalk and Vinegar replenish your Mg? I know I've read it somewhere, but why Vinegar in addition to the Kalk?" That is what got me all turned around and upside down. And yes, I am dumb. Vinegar lowers ph as it is an acid. Lower ph means more acidic, higher ph, basic. That's what, high school chemistry? Embarrassing... Did I mention I hated chemistry?
     
  15. Tholton33

    Tholton33 Well-Known ReefKeeper

    537
    Ratings:
    +0 / 0 / -0
    Kalk + vinegar will not add any Mg, but will help reduce losses of Mg which can occur when you add Kalk to a system that already has a high KH and GH - the vinegar lowers the pH of the Kalk, therefore reducing the amount of precipitation which happens in the tank water, which consumes Mg.
     

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